TRANSFER FREE ENERGIES FOR ALKALI-METAL CHLORIDES IN ETHANOL-WATER AND METHANOL-WATER SOLVENTS FROM EMF MEASUREMENTS.

Title: TRANSFER FREE ENERGIES FOR ALKALI-METAL CHLORIDES IN ETHANOL-WATER AND METHANOL-WATER SOLVENTS FROM EMF MEASUREMENTS.
Identifier: AAI8302532
identifier: 8302532
Creator: MAZZARESE, JOSEPH MICHAEL.
Contributor: Orest Popovych
Date: 1982
Language: English
Publisher: City University of New York.
Subject: Chemistry, Analytical
Abstract: EMF measurements were performed on cells consisting of an alkali-metal amalgam electrode versus a silver-silver chloride electrode in dilute solutions of the alkali-metal chloride. These metals included Li, Na, and K. The ethanol-water and methanol-water solvents ranged from 0% to 100% alcohol by weight.;Transfer activity coefficients and transfer free energies were calculated from the difference between the standard potential of each nonaqueous cell and that of the corresponding aqueous cell. The standard potential of the metal/metal ion electrode versus the standard hydrogen electrode was calculated for the alkali metals in each solvent. Activity coefficients for the alkali-metal chlorides are reported.
Type: dissertation
Source: PQT Legacy CUNY.xlsx
degree: Ph.D.
Program: Chemistry

Media: TRANSFER FREE ENERGIES FOR ALKALI-METAL CHLORIDES IN ETHANOL-WATER AND METHANOL-WATER SOLVENTS FROM EMF MEASUREMENTS.