THE THEORY AND SYNTHESIS OF (2.2.2) PROPELLANE.

Title: THE THEORY AND SYNTHESIS OF (2.2.2) PROPELLANE.
Identifier: AAI8312365
identifier: 8312365
Creator: PROCIV, THEODORE MARK.
Contributor: Joseph J. Dannenberg
Date: 1983
Language: English
Publisher: City University of New York.
Subject: Chemistry, Organic
Abstract: INDO calculations indicated that the triplet state of dimethylene cyclohexane could rearrange to gometrically relaxed triplets which should collapse preferentially to the ground state {lcub}2.2.2{rcub} Propellane. A mercury sensitized photolysis of the dimethylene cyclohexane did in fact result in detectable quantities of the propellane, trapped as 1,4 dibromobicyclo octane. Synthesis of 1,4 dibromobicyclo octane and 1,1,6,6 tetradeuterodimethylene-cyclohexane are presented in the dissertation. Included in the dissertation are the results of INDO calculations of various propellane isomers having nitrogens and borons in the bridgehead positions.
Type: dissertation
Source: PQT Legacy CUNY.xlsx
degree: Ph.D.
Program: Chemistry